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· Ball‐milled, extract‐free whole cell wall samples (40 mg) were prepared in a 5 mm NMR tube and suspended/swelled in dimethyl sulfoxide (DMSO)‐d 6 /pyridine‐d 5 '' (4:1, 500 μl). The MWEL was prepared from ball‐milled material (50–70 mg) as described previously (Chang et al., 1975; Wagner et al., 2007). The material was ...
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· The temperature was then adjusted to either a constant 10°C or to a 20°C/18°C regime. The sampling took place after 0 and 168 h for metabolite analysis and at 0, 1, 6, 12, 24, and 36 h for transcript analysis, respectively. Samples were frozen in liquid nitrogen and powdered in a ball mill. Extraction of semipolar compounds
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· For routine spectrophotometric assays, activities were measured in 50 m m Tris–HCl (pH ), 300 µ m CoA, m m ATP, m m MgCl 2, 50 µ m substrate and 1 µg CoA ligase in a total volume of 100 µl. Inactive protein was boiled for 10 min at 80°C. The reaction was started by addition of substrate and incubated for 1 h at 30°C and 300 rpm.
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